KYIV, Ukraine (AP) – Russian missiles have struck Ukraine’s Black Sea port of Odesa just hours after Moscow and Kyiv signed deals to allow grain exports to resume from there. A Ukrainian spokesperson described Saturday’s attack as “spit in the face” of Turkey and the United Nations, which brokered the deal. The Ukrainian military says two Russian cruise missiles hit the port’s infrastructure and Ukrainian air defenses brought down two others. The Foreign Ministry said Russia would bear full responsibility if the war in Ukraine results in a global food crisis. Elsewhere, Russia fired missiles Saturday at an airfield and a railway in central Ukraine, killing at least three people, while Ukraine launched rocket strikes on river crossings in a Russian-occupied southern region.